NUKLEONIKA 2005, 50(Supplement 2):S59-S63

RADIATION CHEMISTRY IN EXPLORATION OF MARS

Zbigniew P. Zagórski

Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland


Problems of exploration of Mars are seldom connected with radiation research. Improvements in such approach, more and more visible, are reported in this paper, written by the present author working on prebiotic chemistry and origins of life on Earth. Objects on Mars subjected to radiation are very different from those on Earth. Density of the Martian atmosphere is by two orders smaller than over Earth and does not protect the surface of Mars from ionizing radiations, contrary to the case of Earth, shielded by the equivalent of ca. 3 meters of concrete. High energy protons from the Sun are diverted magnetically around Earth, and Mars is deprived of that protection. The radiolysis of martian “air” (95.3% of carbon dioxide) starts with the formation of CO2+, whereas the primary product over Earth is N2+ ion-radical. The lack of water vapor over Mars prevents the formation of many secondary products. The important feature of Martian regolith is the possibility of the presence of hydrated minerals, which could have been formed milliards years ago, when (probably) water was present on Mars. The interface of the atmosphere and the regolith can be the site of many chemical reactions, induced also by intensive UV, which includes part of the vacuum UV. Minerals like sodalite, discovered on Mars can contribute as reagents in many reactions. Conclusions are dedicated to questions of the live organisms connected with exploration of Mars; from microorganisms, comparatively resistant to ionizing radiation, to human beings, considered not to be fit to manned flight, survival on Mars and return to Earth. Pharmaceuticals proposed as radiobiological protection cannot improve the situation. Exploration over the distance of millions of kilometers performed successfully without presence of man, withstands more easily the presence of ionizing radiation.