KINETIC ISOTOPE EFFECTS OF ATOMIC HYDROGEN IN CONDENSED PHASES

A. Plonka

Institute of Applied Radiation Chemistry, Technical University of Lodz, 15 Wróblewskiego Str., 93-590 ŁódŸ


Accounting for the dynamical effects of the host matrix on the guest movements in terms of dispersive kinetics, one finds the rationalization of the inverse isotope effects of atomic hydrogen in condensed media in the vicinity of break points on the Arrhenius plots of rate parameters.