DSC EXAMINATIONS OF HEAVY ION IRRADIATED THIN POLYMER FOILS

K. Cieśla1, Ch. Trautmann2, E. F. Vansant3

1 Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw, Poland,
2 Gesellschaft fuer Schwerionenforschung mbH. Planckstr. 1, D64220, Darmstadt, FRG
3 University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk, Belgium


Thin films of PETP (Hostaphan RN), PC Makrofol N, PI Kapton H, original and heavy ions irradiated, were investigated by DSC method in nitrogen flow. Differences were observed between DSC traces of initial and irradiated foils. In the case of PETP premelting behaviour was recorded during heating of irradiated samples. The effect is related to the appearence of a disordered phase. The influence of irradiation conditions on the results was examined. In the case of PC and PI a decrease in thermal resistivity was found. The differences in DSC traces of unirradiated and irradiated foils are brought about by changes in film ordering. The decrease in ordering was confirmed for PETP by WAXS method and density data. The DSC method proved to be very suitable for this kind of study.